Your GPU cannot do regular 8k video in VR, let along encoding it and sending the signal to the headset at the same time.
Doing the DLNA is easy. Download Plex server from plex.tv and add your videos to its library, enable the DLNA in settings, and you are good to go.
The only thing you need to be aware is that every device connected to your wifi might also see your shared video files. So if your family members come to your home, disable the DLNA.