Make a .bat file
put this in it, and replace the file location and name to yours. must use forward slash, don't use ambiguous characters nor spaces.
start "" deovr://E:/Porn/VR/18VR/18VR_Boneward_Bound_Zazie_Skymm_Selvaggia_Babe_1920p.mp4
You can add custom icon/thumb to the file, like a screenshot of the video...